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申请号:201911169794.3 公开号:CN110947375A 主分类号:B01J23/28
申请人:【中文】红宝丽集团股份有限公司【EN】HONGBAOLI GROUP Co.,Ltd. 申请日:2019.11.26 公开日:2020.04.03
摘要:【中文】本申请公开了一种用于制备环氧丙烷的催化剂,其包含0.05~10wt%的TiO2、0.5~2.9wt%的M1、0.05~0.5wt%的M2,其余成分为SiO2;M1为Al2O3、SO3或Cr2O3中的至少一种;M2为P、W或Mo中的至少一种。还公开了该催化剂的制备方法,步骤为:(Ⅰ)将硅粉、增塑剂、胶粘剂、调胶剂及M2混合,然后成为成型物,将成型物干燥、焙烧后制得硅条;(Ⅱ)向反应器中加入硅条,并送入钛源进行反应,在用含M1的溶液浸泡,完成浸泡后排空;(Ⅲ)用酸液浸泡并排空后,进行清洗,干燥后即制得该催化剂。该催化剂极大提高中间产物异丙苯与α,α‑二甲基苄醇的纯度,以利于物料的充分使用。该方法能够顺利完成该催化剂的生产。 【EN】The application discloses a catalyst for preparing propylene oxide, which comprises 0.05-10 wt% of TiO20.5 to 2.9 wt% of M1, 0.05 to 0.5 wt% of M2, and the balance of SiO2(ii) a M1 is Al2O3、SO3Or Cr2O3At least one of; m2 is P, W or at least one of Mo. Also discloses the catalystThe preparation method of the catalyst comprises the steps of (I) mixing silicon powder, a plasticizer, an adhesive, a glue mixing agent and M2, then forming a forming object, drying and roasting the forming object to obtain a silicon strip, (II) adding the silicon strip into a reactor, feeding a titanium source for reaction, soaking the silicon strip in a solution containing M1, emptying the silicon strip after soaking, and (III) soaking the silicon strip in an acid solution, emptying the silicon strip, cleaning the silicon strip, and drying the silicon strip to obtain the catalyst.
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