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申请号:202010003118.5 公开号:CN111122546A 主分类号:G01N21/65
申请人:【中文】北京科技大学【EN】University OF SCIENCE AND TECHNOLOGY BEIJING 申请日:2020.01.02 公开日:2020.05.08
摘要:【中文】本发明公开了一种缓蚀剂分子的定性、半定量检测方法。本发明利用表面增强拉曼效应放大金属及其合金表面吸附的缓蚀剂分子的拉曼光谱信号,实现缓蚀剂分子的定性和半定量检测,所述方法首先将金属及其合金浸泡在一定浓度的缓蚀剂溶液中,一段时间后将试样拿出,在其表面沉积或覆盖一层等离激元纳米材料薄膜,之后利用拉曼光谱仪检测试样表面吸附的缓蚀剂分子的拉曼信号。本发明利用表面增强拉曼效应显著放大缓蚀剂分子的拉曼信号,可以实现微量、痕量缓蚀剂的高灵敏度检测,本发明有助于促进缓蚀机理的深入分析,这在腐蚀与防护研究领域具有广阔的应用前景。 【EN】The invention discloses a qualitative and semi-quantitative detection method of corrosion inhibitor molecules. The method comprises the steps of firstly soaking the metal and the metal alloy in corrosion inhibitor solution with certain concentration, taking out a sample after a period of time, depositing or covering a layer of plasmon nanometer material film on the surface of the sample, and then detecting the Raman signal of the corrosion inhibitor molecules adsorbed on the surface of the sample by using a Raman spectrometer. The invention obviously amplifies the Raman signal of the corrosion inhibitor molecule by utilizing the surface enhanced Raman effect, can realize the high-sensitivity detection of trace corrosion inhibitor, is beneficial to promoting the deep analysis of the corrosion inhibition mechanism, and has wide application prospect in the research field of corrosion and protection.
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