摘要：【中文】本发明提供一种利用单糖合成1,6‑己二醇的方法，为：将单糖置于水中，在氢气气氛和第一催化剂的作用下，进行连续脱水‑加氢反应，将反应液与第一催化剂分离，浓缩反应液，在氢气气氛和第二催化剂的作用下，继续反应，得到1,6‑己二醇。本发明的方法相较已有1,6‑己二醇的合成方法有过程简单、不引入液体酸、无废酸排放、催化剂可循环再利用等优点。本发明方法中葡萄糖可实现完全转化，1,6‑己二醇的收率最高可达50％。 【EN】The invention provides a method for synthesizing 1, 6-hexanediol by using monosaccharide, which comprises the following steps: placing monosaccharide in water, carrying out continuous dehydration-hydrogenation reaction under the action of a hydrogen atmosphere and a first catalyst, separating a reaction solution from the first catalyst, concentrating the reaction solution, and continuously reacting under the action of the hydrogen atmosphere and a second catalyst to obtain the 1, 6-hexanediol. Compared with the existing synthesis method of 1, 6-hexanediol, the method has the advantages of simple process, no introduction of liquid acid, no waste acid discharge, recyclable catalyst and the like. The glucose can be completely converted in the method, and the yield of the 1, 6-hexanediol can reach 50 percent at most.

摘要：【中文】本发明提供一种利用纤维素制备羟基丁酮的方法。包括：将纤维素置于水中，在氢气气氛和催化剂的作用下，反应，得到1‑羟基‑2‑丁酮和3‑羟基‑2‑丁酮。所述催化剂由组分A和组分B组成；组分A为钨基化合物(主要活性组分)，组分B通过将8、9、10族过渡金属铁、钴、镍、钌、铑、钯、铱、铂中的一种或几种作为第二金属组分负载于一种或多种多孔材料上制备得到。催化剂能够在200‑260℃，反应体系初始压力为20atm－80atm的水热条件下实现纤维素高效、高选择性、高收率催化转化为1‑羟基‑2‑丁酮。与现有的1,2‑丁二醇为反应原料的1‑羟基‑2‑丁酮的工业合成路线相比较，本发明所提供的反应具有原料为可再生资源、反应过程绿色环境友好、产物附加经济价值高。 【EN】The invention provides a method for preparing hydroxy butanone by using cellulose. The method comprises the following steps: placing cellulose in water, and reacting under the action of hydrogen atmosphere and catalyst to obtain 1-hydroxy-2-butanone and 3-hydroxy-2-butanone. The catalyst consists of a component A and a component B; the component A is a tungsten-based compound (main active component), and the component B is prepared by taking one or more of transition metals of groups 8, 9 and 10, such as iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium and platinum, as a second metal component and loading the second metal component on one or more porous materials. The catalyst can realize the catalytic conversion of cellulose into 1-hydroxy-2-butanone with high efficiency, high selectivity and high yield under the hydrothermal condition of 200-260 ℃ and the initial pressure of a reaction system of 20-80 atm. Compared with the existing industrial synthesis route of 1-hydroxy-2-butanone taking 1, 2-butanediol as a reaction raw material, the reaction provided by the invention has the advantages that the raw material is renewable resources, the reaction process is green and environment-friendly, and the added economic value of the product is high.

摘要：【中文】本发明提供的一种由戊醛糖二酸制备戊二酸的方法，包括如下步骤：第一步，在水溶液中，戊醛糖二酸在催化剂A上，得到2,4‑二羟基戊二酸；第二步，在催化剂B上，进一步得到戊二酸。本发明使用水作为反应溶剂，不额外引入卤族元素，且用到的多相催化剂可以回收利用，整个生产过程比较绿色。 【EN】The invention provides a method for preparing glutaric acid from aldopentose diacid, which comprises the following steps: firstly, in aqueous solution, aldopentose diacid is on a catalyst A to obtain 2, 4-dihydroxy glutaric acid; in the second step, glutaric acid is further obtained on catalyst B. According to the invention, water is used as a reaction solvent, no extra halogen element is introduced, the used heterogeneous catalyst can be recycled, and the whole production process is relatively green.

摘要：【中文】本发明公开了一种生物质基壬二酸的制备方法。该方法包括下述步骤：1)在水溶液中，5‑甲酰基‑2‑呋喃甲酸和丙酮酸在碱催化剂上发生羟醛缩合反应，生成C9缩合产物；2)在加氢催化剂上，C9缩合产物发生加氢反应，生成C9饱和产物；3)在氢解催化剂上，C9饱和产物发生氢解反应，生成壬二酸。本发明以生物质基平台分子为反应原料，使用水作为反应溶剂，采用易于回收利用的多相催化剂，且催化剂具有较高的催化活性和循环稳定性，反应过程绿色无污染，对环境友好。 【EN】The invention discloses a preparation method of biomass-based azelaic acid. The method comprises the following steps: 1) in aqueous solution, 5-formyl-2-furancarboxylic acid and pyruvic acid are subjected to aldol condensation reaction on an alkali catalyst to generate a C9 condensation product; 2) on a hydrogenation catalyst, carrying out hydrogenation reaction on the C9 condensation product to generate a C9 saturated product; 3) the saturated product of C9 was subjected to hydrogenolysis over a hydrogenolysis catalyst to produce azelaic acid. According to the invention, the biomass-based platform molecules are used as reaction raw materials, water is used as a reaction solvent, a heterogeneous catalyst which is easy to recycle is adopted, the catalyst has high catalytic activity and circulation stability, and the reaction process is green and pollution-free and is environment-friendly.

摘要：【中文】本发明提供的一种由己醛糖二酸制备2,5‑二羟基己二酸和己二酸的方法。制备2,5‑二羟基己二酸的方法，包括如下步骤：在催化剂A存在下，使己醛糖二酸在水溶液中与氢气进行反应1，得到2,5‑二羟基己二酸。制备己二酸的方法，包括如下步骤：1)在催化剂A存在下，使己醛糖二酸在水溶液中与氢气进行反应1，得到2,5‑二羟基己二酸；2)在催化剂B存在下，使所述2,5‑二羟基己二酸进行反应2，得到己二酸。本发明使用水作为反应溶剂，不但反应过程绿色无污染，对环境友好；还降低了生产成本。 【EN】The invention provides a method for preparing 2, 5-dihydroxy adipic acid and adipic acid from aldohexose diacid. A method of preparing 2, 5-dihydroxyadipic acid comprising the steps of: reacting 1 an aldohexose diacid with hydrogen in an aqueous solution in the presence of a catalyst A to obtain 2, 5-dihydroxyadipic acid. A process for the preparation of adipic acid comprising the steps of: 1) reacting 1 aldohexose diacid with hydrogen in an aqueous solution in the presence of a catalyst A to obtain 2, 5-dihydroxyadipic acid; 2) reacting 2 the 2, 5-dihydroxyadipic acid in the presence of a catalyst B to obtain adipic acid. The method uses water as a reaction solvent, so that the reaction process is green and pollution-free and is environment-friendly; and the production cost is also reduced.

摘要：【中文】本发明公开一种用于塑料挤出机的带有偏转分流孔的挤出模具，包括芯模组件，沿前后方向延伸；分流组件，包括分流锥和分流环，分流锥、分流环以及芯模组件自前至后依次同轴固定连接；口模组件，同轴固定套设在芯模组件和分流组件的外侧，口模组件具有物料入和，口模组件与分流锥之间设有分流流道，口模组件与芯模组件之间设有挤出流道，分流环具有多个贯通该分流环的分流孔，物料入口、分流流道、多个分流孔以及挤出流道依次相连通，多个分流孔沿圆周方向阵列布置在分流环上，各个分流孔的延伸方向与前后方向成角度偏转布置。有效避免分流线的产生，最终使得制品的表面质量得以提高。 【EN】The invention discloses an extrusion die with a deflection shunting hole for a plastic extruder, which comprises a core die component, a deflection shunting hole and a guide rail, wherein the core die component extends along the front-back direction; the shunt assembly comprises a shunt cone and a shunt ring, and the shunt cone, the shunt ring and the core mold assembly are sequentially and coaxially fixedly connected from front to back; the bush module, coaxial fixed cover is established in the outside of mandrel module and reposition of redundant personnel subassembly, the bush module has the material to go into with, be equipped with the reposition of redundant personnel runner between bush module and the reposition of redundant personnel awl, be equipped with between bush module and the mandrel module and extrude the runner, the reposition of redundant personnel ring has a plurality of diffluence holes that link up this diffluence ring, the material entry, the reposition of redundant personnel runner, a plurality of diffluence holes and extrusion runner are linked together in proper order, a plurality of diffluence holes are arranged on the diffluence ring along the circumferencial direction array, the extending direction and the fore-. Effectively avoid the production of flow distribution line, finally make the surface quality of goods improve.

摘要：【中文】本发明提供了一种截骨导向器及截骨手术器械，截骨导向模块包括第一截骨导向块和第二截骨导向块，第一截骨导向块与第二截骨导向块间隔固定在待截骨上，所述间隔包括依次连接的第一间隙、第二间隙和第三间隙，第一间隙和第三间隙位于第二间隙所在直线的两侧。所述截骨导向器及截骨手术器械具有良好的抗旋和髓腔同心的优点，其能够实现截骨导向和截骨长度测量，从而保障截骨面的平整，使得待截骨两端接触稳定，有利于力的有效传导，减少骨质疏松，促进骨骼发育，使得骨骼可以尽早愈合，术后病人能够尽快下地行走，实现患者早期负重。 【EN】The invention provides an osteotomy guide device and an osteotomy surgical instrument, wherein an osteotomy guide module comprises a first osteotomy guide block and a second osteotomy guide block, the first osteotomy guide block and the second osteotomy guide block are fixed on a bone to be cut at intervals, the intervals comprise a first gap, a second gap and a third gap which are sequentially connected, and the first gap and the third gap are positioned on two sides of a straight line where the second gap is positioned. The osteotomy guider and the osteotomy surgical instrument have the advantages of good anti-rotation and medullary cavity concentricity, can realize osteotomy guiding and osteotomy length measurement, thereby ensuring the smoothness of an osteotomy surface, ensuring the contact stability of two ends of an osteotomy to be cut, being beneficial to effective force conduction, reducing osteoporosis, promoting bone development, enabling bones to heal as early as possible, enabling postoperative patients to walk on the ground as soon as possible, and realizing early load bearing of the patients.

摘要：【中文】一种机械工厂用的小型机械加工工具清洗设备，包括座板，座板的顶面左侧固定安装竖向的第一支撑杆，第一支撑杆靠近座板中部的一侧轴承安装水平的第一转轴，第一转轴的外端固定安装与之同轴的转盘，转盘设有出液结构，座板的顶面右侧固定安装输出轴水平的双输出轴电机。本发明采用一个双输出轴电机作为动力来源，在实现螺管的水平移动与转动的同时，且还通过滚轮对管状加工工具的稳定夹持，同时还能实现对螺管内进液和向外部进行出液喷洒操作，且采用螺管与滚轮的相互配合实现对管状加工工具的夹持并带动其转动，采用管盖与螺管发生相对转动的方式，采用出水喷头对管状加工工具内壁进行螺旋式喷射清洗的方式，整个清洗过程快捷方便。 【EN】The utility model provides a small-size machining tool cleaning equipment that machinery factory used, includes the bedplate, the vertical first bracing piece of top surface left side fixed mounting of bedplate, the first bracing piece is close to the first pivot of a side bearing installation horizontally in bedplate middle part, the outer end fixed mounting of first pivot with coaxial carousel thereof, the carousel is equipped with out the liquid structure, the top surface right side fixed mounting output shaft horizontally dual output shaft motor of bedplate. The invention adopts a motor with double output shafts as a power source, realizes the horizontal movement and rotation of the solenoid, simultaneously stably clamps the tubular processing tool through the roller, simultaneously can realize the liquid inlet and liquid outlet spraying operation to the outside in the solenoid, realizes the clamping of the tubular processing tool and drives the tubular processing tool to rotate by adopting the mutual matching of the solenoid and the roller, adopts the mode that the pipe cover and the solenoid rotate relatively, adopts the mode that the water outlet nozzle carries out spiral jet cleaning on the inner wall of the tubular processing tool, and has quick and convenient whole cleaning process.

摘要：【中文】本发明公开了一种负载腐蚀响应剂的纳米容器及其制备方法与应用。所述负载腐蚀响应剂的纳米容器的制备方法包括：将介孔二氧化硅与分散溶剂混合均匀形成二氧化硅分散液；之后向所述二氧化硅分散液中加入腐蚀响应剂溶液混合均匀，经后处理制得负载腐蚀响应剂的二氧化硅；最后将所述负载腐蚀响应剂的二氧化硅与壳聚糖溶液混合均匀，之后向混合溶液中加入三聚磷酸钠溶液混合均匀，经后处理制得负载腐蚀响应剂的纳米容器。本发明制备的腐蚀自预警与自修复的双功能防腐涂层灵敏度高，可迅速检测出金属表面的局部腐蚀并在腐蚀界面处形成缓蚀膜发挥自修复功能，在材料腐蚀防护评价及检测中具有良好的应用前景。 【EN】The invention discloses a nano container loaded with a corrosion response agent, and a preparation method and application thereof. The preparation method of the nano container loaded with the corrosion response agent comprises the following steps: uniformly mixing mesoporous silica with a dispersing solvent to form a silica dispersion liquid; adding a corrosion response agent solution into the silicon dioxide dispersion liquid, uniformly mixing, and performing post-treatment to obtain silicon dioxide loaded with a corrosion response agent; and finally, uniformly mixing the silicon dioxide loaded with the corrosion response agent with a chitosan solution, then adding a sodium tripolyphosphate solution into the mixed solution, uniformly mixing, and performing aftertreatment to obtain the nano container loaded with the corrosion response agent. The corrosion self-warning and self-repairing dual-functional anticorrosive coating prepared by the invention has high sensitivity, can quickly detect local corrosion on the metal surface and form a corrosion inhibition film at a corrosion interface to play a self-repairing function, and has good application prospect in material corrosion protection evaluation and detection.

摘要：【中文】本发明公开了随机多轴载荷下考虑裂纹闭合效应的全寿命预测方法，涉及到随机多轴疲劳裂纹扩展及寿命预测领域，该方法步骤为：(1)对随机载荷进行Wang‑Brown循环计数，得到多个循环，选取剪应力范围最大时的面为临界面，在临界面上计算使裂纹扩展的驱动力；(2)利用提出的有效应力强度因子公式计算等效应力强度因子；(3)利用改进后的Paris公式计算每个循环的裂纹扩展量，求得达到临界裂纹长度时的寿命，即为全寿命；(4)寿命预测值与试验所得寿命进行比较。结果表明该方法可以较好的预测随机多轴载荷下裂纹扩展寿命。 【EN】The invention discloses a full-life prediction method considering a crack closure effect under random multi-axis load, which relates to the field of random multi-axis fatigue crack propagation and life prediction, and comprises the following steps: (1) performing Wang-Brown cycle counting on the random load to obtain a plurality of cycles, selecting a surface with the largest shear stress range as a critical surface, and calculating a driving force for expanding the crack on the critical surface; (2) calculating an equivalent stress intensity factor by using a proposed effective stress intensity factor formula; (3) calculating the crack expansion amount of each cycle by using an improved Paris formula, and obtaining the service life when the critical crack length is reached, namely the total service life; (4) the predicted life is compared with the life obtained by the test. The result shows that the method can better predict the crack propagation life under random multi-axis load.