摘要：【中文】本发明公开了提供一种含氯的氟碳防水防油剂共聚物乳液及其聚合方法，其含有以下组分，乳化剂，由四到六种不同亲水亲油平衡值(HLB值)的表面活性剂组成；聚合单体，全氟烷基乙基丙烯酸(甲)酯，全氟辛基乙基丙烯酸酯，全氟辛基乙基丙烯酸甲酯，全氟己基乙基丙烯酸酯，全氟己基乙基丙烯酸甲酯中的至少一种；由通式CH₂＝CCl(C＝O)‑O‑C_nH_2n+1表示的氯代丙烯酸酯，其中n为12，14，16，18，20，22；功能性单体。该含氯的氟碳防水防油剂共聚物乳液利用含氯基团电负性强的特性，提高防水剂对织物的吸附，提高防水效果以及耐水洗性，长链的氯代丙烯酸酯相对短链的聚乙烯对防水防油的效果影响小，反应过程中不需要加压且无氯乙烯这类有毒物质。 【EN】The invention discloses a copolymer emulsion of fluorine-carbon water-proof and oil-proof agent containing chlorine and its polymerization method, which comprises the following components, emulsifier, four to six kinds of surface active agents with different hydrophile-lipophile balance (HLB value); at least one of a polymerized monomer, perfluoroalkyl ethyl acrylate (methyl), perfluoro octyl ethyl acrylate, perfluoro octyl methyl ethyl acrylate, perfluoro hexyl ethyl acrylate and perfluoro hexyl methyl ethyl acrylate; from the general formula CH₂＝CCl(C＝O)‑O‑C_nH_2n+1Chloroacrylates of formula (I) wherein n is 12, 14, 16, 18, 20, 22; a functional monomer. The copolymer emulsion of the fluorine-containing fluorocarbon waterproof and oil-proof agent utilizes the characteristic of strong electronegativity of chlorine-containing groups to improve the adsorption of the waterproof agent to fabrics and improve the waterproof effect and the water washing resistance, the long-chain chloroacrylate has little influence on the waterproof and oil-proof effects relative to the short-chain polyethylene, and no toxic substances such as vinyl chloride are required to be pressurized in the reaction process.

摘要：【中文】本发明公开了一种含氯的无氟防水剂共聚物乳液及其聚合方法，其含有以下组分，乳化剂，由四到六种不同亲水亲油平衡值的表面活性剂组成；长链烷基丙烯酸酯，包含丙烯酸辛酯，甲基丙烯酸辛酯，丙烯酸癸酯，甲基丙烯酸癸酯，丙烯酸月桂酯，甲基丙烯酸月桂酯，丙烯酸十四烷基酯，甲基丙烯酸十四烷基酯，丙烯酸十六烷基酯，甲基丙烯酸十六烷基酯，丙烯酸十八烷基酯，甲基丙烯酸十八烷基酯，丙烯酸二十二烷基酯，甲基丙烯酸二十二烷基酯中的一种或几种。该含氯的无氟防水剂共聚物乳液利用含氯基团电负性强的特性，提高防水剂对织物的吸附，提高防水效果以及耐水洗性，长链的氯代丙烯酸酯相对短链的聚乙烯对防水防油的效果影响小。 【EN】The invention discloses a chlorine-containing fluoride-free waterproofing agent copolymer emulsion and a polymerization method thereof, wherein the chlorine-containing fluoride-free waterproofing agent copolymer emulsion comprises the following components of an emulsifier, a surfactant and a water-soluble polymer, wherein the emulsifier is composed of four to six surfactants with different hydrophilic-lipophilic balance values; long-chain alkyl acrylate containing one or more of octyl acrylate, octyl methacrylate, decyl acrylate, decyl methacrylate, lauryl acrylate, lauryl methacrylate, tetradecyl acrylate, tetradecyl methacrylate, hexadecyl acrylate, hexadecyl methacrylate, octadecyl acrylate, octadecyl methacrylate, docosyl acrylate and docosyl methacrylate. The chlorine-containing fluorine-free water repellent copolymer emulsion utilizes the characteristic of strong electronegativity of chlorine-containing groups to improve the adsorption of the water repellent to fabrics and improve the water-proof effect and water washing resistance, and long-chain chloroacrylate has little influence on the water-proof and oil-proof effects compared with short-chain polyethylene.